Arctic freshwater ostracods from modern periglacial environments in the Lena River Delta (Siberian Arctic,Russia): geochemical applications for palaeoenvironmental reconstructions     

Sebastian?WetterichEmail author  Lutz?Schirrmeister  Hanno?Meyer  Finn?Andreas?Viehberg  Andreas?Mackensen 《Journal of Paleolimnology》2008,39(4):427-449

The aim of this study is to describe ostracods from freshwater habitats in the Siberian Arctic in order to estimate the present-day relationships between the environmental setting and the geochemical properties of ostracod calcite. A special focus is on the element ratios (Mg/Ca, Sr/Ca), and the stable isotope composition (δ¹⁸O, δ¹³C), in both ambient waters and ostracod calcite. The most common species are Fabaeformiscandona pedata and F. harmsworthi with the highest frequency in all studied waters. Average partition coefficients D(Sr) of F. pedata are 0.33 ± 0.06 (1σ) in females, and 0.32 ± 0.06 (1σ) in males. A near 1:1 relationship of δ¹⁸O was found, with a mean shift of Δ_mean = 2.2‰ ± 0.5 (1σ) to heavier values in ostracod calcite of F. pedata as compared to ambient waters. The shift is not dependent on δ¹⁸O_water, and is caused by metabolic (vital) and temperature effects. Temperature-dependence is reflected in the variations of this shift. For ostracod calcite of F. pedata a vital effect as compared to inorganic calcite in equilibrium was quantified with 1.4‰. Results of this study are valuable for the palaeoenvironmental interpretation of geochemical data of fossil ostracods from permafrost deposits.  相似文献   

Fusion of multi‐resolution surface (terrestrial laser scanning) and subsurface geodata (ERT,SRT) for karst landform investigation and geomorphometric quantification     

Christoph Siart  Markus Forbriger  Erich Nowaczinski  Stefan Hecht  Bernhard Höfle 《地球表面变化过程与地形》2013,38(10):1135-1147

A multi‐method research design based on terrestrial laser scanning, GIS, geophysical prospecting (electrical resistivity tomography, refraction seismics) and sedimentology is applied for the first time to investigate enclosed karst depressions in an integrated way. Fusing multi‐resolution surface and subsurface geodata provides profound insights into the formation, geometry and geomorphologic processes of dolines. The studied landforms, which are located in the Dikti Mountains of East Crete, are shown to be filled by loose sediments of thicknesses of up to 30 m that mainly consist of fine‐grained material overlying solid bedrock at depths below 35 to 45 m. By combining subsurface observations with geomorphometric calculations, local doline genesis can be traced back to initial collapse of fractured bedrock followed by subsequent infilling with colluvials. In order to define crucial methodological requirements and guidelines for data fusion, both the impact of different elevation models and the influence of data resolution are assessed. Surface volumes of depressions derived by the digital surface model are 7–21% higher than the results obtained from the terrain model due to vegetation. Similarly, estimates of infill volume calculated on the basis of geophysical outcomes and elevation data differ by up to 13%. Calculations of the landforms' current volumes (i.e. total surface and subsurface volume), however, are fairly insensitive to raster resolution. Hence, the distinct geomorphologic properties of landforms (e.g. shape, terrain roughness, slope inclination) substantially determine the geomorphometric analysis of both surface and subsurface data. As shown by the findings, data fusion to integrate digital terrain, geophysical and sedimentological datasets of varied resolutions benefits geomorphologic studies and helps provide a comprehensive image of landforms. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

A Raman spectroscopic study on the structural disorder of monazite–(Ce)     

Katja Ruschel  Lutz Nasdala  Andreas Kronz  John M. Hanchar  Daniel M. T?bbens  Radek ?koda  Friedrich Finger  Andreas M?ller 《Mineralogy and Petrology》2012,105(1-2):41-55

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.  相似文献   

Direct terrestrial-marine correlation demonstrates surprisingly late onset of the last interglacial in central Europe     

Mark J. Sier  Wil Roebroeks  Corrie C. Bakels  Enrico Brühl  Dimitri De Loecker  Norbert Hesse  Lutz Kindler  Thomas Laurat  Herman J. Mücher  Kirsty E.H. Penkman  Douwe J.J. van Hinsbergen 《Quaternary Research》2011,75(1):213-218

An interdisciplinary study of a small sedimentary basin at Neumark Nord 2 (NN2), Germany, has yielded a high-resolution record of the palaeomagnetic Blake Event, which we are able to place at the early part of the last interglacial pollen sequence documented from the same section. We use this data to calculate the duration of this stratigraphically important event at 3400 ± 350 yr. More importantly, the Neumark Nord 2 data enables precise terrestrial-marine correlation for the Eemian stage in central Europe. This shows a remarkably large time lag of ca. 5000 yr between the MIS 5e ‘peak’ in the marine record and the start of the last interglacial in this region.  相似文献   

Geological evolution of the West Luzon Basin (South China Sea,Philippines)     

Jashar?ArfaiEmail author  Dieter?Franke  Christoph?Gaedicke  Rüdiger?Lutz  Michael?Schnabel  Stefan?Ladage  Kai?Berglar  Mario?Aurelio  Jennie?Montano  Nicole?Pellejera 《Marine Geophysical Researches》2011,32(3):349-362

Interpretation of deep 2-D multi-channel seismic data sheds insights into the geological evolution of the West Luzon Basin, Philippines. This basin is a sediment-filled trough that is located between the island of Luzon and the outer arc high of the west Luzon subduction zone. High-amplitude, low-frequency reflection bands mark the acoustic basement. The basement, at about 6 s (TWT), is dissected by normal faults with some of them being inverted in a later phase of deformation. The sedimentary successions, overlying the basement are stratified with partly chaotic structures and discontinuous reflectors. Five regional unconformities separate major stratigraphic units. Grid calculations of our seismic data reveal variations in the sedimentation pattern of the basin with a shift of the deposition centre from east to west and backwards during formation. A distinct bottom-simulating reflector is commonly observed. Because the northern boundary of the continental fragments to the South of the West Luzon Basin is unclear we speculate that the basin may be (partly) underlain by continental crust. The continental crust was affected by rifting prior to and during the opening of the South China Sea and the basin was overprinted at a later stage by a forearc structural setting when subduction was initiated.  相似文献   

Factors affecting the Nd3+ (REE3+) luminescence of minerals     

Christoph Lenz  Dominik Talla  Katja Ruschel  Radek Škoda  Jens Götze  Lutz Nasdala 《Mineralogy and Petrology》2013,107(3):415-428

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.  相似文献   

Polyfluorinated compounds in waste water treatment plant effluents and surface waters along the River Elbe, Germany   总被引：4，自引：0，他引：4  

Lutz Ahrens  Sebastian Felizeter  Renate Sturm  Zhiyong Xie  Ralf Ebinghaus 《Marine pollution bulletin》2009,58(9):1326-1333

Polyfluorinated compounds (PFCs) were investigated in waste water treatment plant (WWTP) effluents and surface waters of the River Elbe from samples collected in 2007. Concentrations of various PFCs, including C₄–C₈ perfluorinated sulfonates (PFSAs), C₆ and C₈ perfluorinated sulfinates, 6:2 fluorotelomer sulfonate, C₅–C₁₃ perfluorinated carboxylic acids (PFCAs), C₄ and C₈ perfluoroalkyl sulfonamides and 6:2, 8:2 and 10:2 unsaturated fluorotelomercarboxylic acids were quantified. ∑PFC concentrations of the river water ranged from 7.6 to 26.4 ng L⁻¹, whereas ∑PFC concentrations of WWTP effluents were approximately 5–10 times higher (30.5–266.3 ng L⁻¹), indicating that WWTPs are potential sources of PFCs in the marine environment. PFC patterns of different WWTP effluents varied depending on the origin of the waste water, whereas the profile of PFC composition in the river water was relatively constant. In both kinds of water samples, perfluorooctanoic acid (PFOA) was the major PFC, whereas perfluorobutane sulfonate (PFBS) was the predominant PFSA.  相似文献   

First results from SPIFFI. I: The Galactic Center     

M. Horrobin  F. Eisenhauer  M. Tecza  N. Thatte  R. Genzel  R. Abuter  C. Iserlohe  J. Schreiber  A. Schegerer  D. Lutz  T. Ott  R. Schdel 《Astronomische Nachrichten》2004,325(2):88-91

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The use of proxy chemical records in Coral skeletons to ascertain past environmental conditions in Florida Bay     

Peter Koenraad Swart  Genevieve Healy  Lisa Greer  Michael Lutz  Amel Saied  Daniel Anderegg  Richard E. Dodge  David Rudnick 《Estuaries and Coasts》1999,22(2):384-397

This paper will discuss the use of chemical proxies in coral skeletons to reconstruct the history of salinity (from the δ¹⁸O of the skeleton) and nutrients in the water (from the δ¹³C) in Florida Bay between 1824 and 1994. Monthly salinity and water temperature data collected since 1989 were used to establish a correlation between salinity, temperature, and the δ¹⁸O of the skeleton of the coralSolenastrea bournoni from Lignumvitae Basin in Florida Bay. This relationship explains over 50% of the variance in the δ¹⁸O of the skeleton. Assuming that interannual variations in the temperature of the water are small, we have applied this relationship to the δ¹⁸O measured in the coral skeleton collected from Lignumvitae Basin which has a record between 1824 and 1993. These data provide a revised estimate of salinity variation in Lignumvitae Basin for the period when historical records for salinity were not available, and show that the highest salinity events occurred in the past 30 yr. Using the relationships between the salinity in Lignumvitate Basin and other basins, obtained using a modern dataset, we are able to estimate ranges in salinity for other portions of Florida Bay. Skeletons of specimens of the coral speciesSiderastrea radians collected from other areas of Florida Bay show similar patterns in the δ¹⁸O over the past 10 yr, indicating that corals in most portions of Florida Bay are recording salinity variations in their skeletons and therefore support the idea that salinity variations in different portions of Florida Bay can be related. Fluorescence analysis of the coral from Lignumvitae Basin shows a large change in the magnitude of the 10-yr signal coincident with the construction of the railway, confirming that this event had a significant impact upon Florida Bay. The δ¹³C of the coral skeletons reveals a long-term history of the oxidation of organic material, fixation of carbon by photosynthesis (algal blooms), and the intrusion of marine water into the bay. Since the construction of the railway from Miami to Key West there has been a long-term decrease in the δ¹³C of the coral skeleton from Lignumvitae Basin, suggesting the increased oxidation of organic material in this area. This decrease in δ¹³C appears to have reached a minimum value around 1984 and has increased since this time in the western portions of Florida Bay. The increase may be related to the algal blooms prevalent in the area or alternatively could result from intrusion of more marine water. In the eastern areas, a small increase in the δ¹⁸C between 1984 and 1988 was followed by further decline suggesting more oxidation of organic material. We have also attempted to use the concentration of barium in the coral skeleton as a proxy indicator of the nutrient status in Florida Bay.  相似文献   

Large-Scale and Mesoscale Distribution of Plankton Biomass and Metabolic Activity in the Northeastern Central Atlantic     

Santiago Hernández-León  Lutz Postel  Javier Arístegui  May Gómez  María Fernanda Montero  Santiago Torres  Carlos Almeida  Eugen Kühner  Ullrich Brenning  Eberhard Hagen 《Journal of Oceanography》1999,55(4):471-482

Plankton biomass and indices of metabolism and growth [electron transport system (ETS), glutamate dehydrogenase (GDH) and aspartate transcarbamylase (ATC) activities] were studied over a 2,800 km east-west section of the tropical North Atlantic Ocean (21°N) in <200, 200–500 and >;500 µm size classes. On the large-scale, zooplankton (>;200 µm) enzymatic activities increased westward in the study section, where large cyanobacteria chains (Trichodesmium spp.) were observed. Parallel to it, an increase in medium calanoids (1–2 mm length) was observed towards the western part of the transect, whereas small calanoids (<1 mm) were dominant throughout the boundary area of the subtropical gyre. Microplankton ETS and mesoplankton ETS and ATC activities seemed to match the wave length of low frequency waves. Our results suggest that such waves are related to the observed enhancement of metabolic activity of micro- and mesoplankton. The large-scale and mesoscale variability observed give evidence of the inadequacy of assuming a steady-state picture of the euphotic zone of tropical and subtropical waters.  相似文献